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Formula Sheets / Chemistry

Chapter 8

Ionic Equilibrium

Revise with flashcards Download this chapter (PDF) All Chemistry formulas (PDF)
Acids, bases and pHBuffers and salt hydrolysisSolubility product

Acids, bases and pH

  • pH=−log[H+],Kw​=[H+][OH−]=10−14 (25∘C),pH+pOH=14
  • Weak acid (Ostwald)

    α=CKa​​​,[H+]=Ka​C​,pH=21​(pKa​−logC)
  • Ka​Kb​=Kw​ (conjugate pair)

Buffers and salt hydrolysis

  • Henderson

    pH=pKa​+log[acid][salt]​;pOH=pKb​+log[base][salt]​
  • Weak acid + strong base salt

    pH=7+21​(pKa​+logC)
  • Strong acid + weak base salt

    pH=7−21​(pKb​+logC)
  • Weak acid + weak base salt

    pH=7+21​(pKa​−pKb​)

Solubility product

  • Ax​By​:  Ksp​=xxyysx+y
  • AB: Ksp​=s2;AB2​: Ksp​=4s3;AB3​: Ksp​=27s4
  • Precipitation

    ionic product>Ksp​ ⇒ precipitate
  • Common ion

    solubility falls: e.g. s=[common ion]Ksp​​ for AB
Chemical EquilibriumRedox Reactions