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Formula Sheets / Chemistry

Chapter 5

Thermodynamics

Revise with flashcards Download this chapter (PDF) All Chemistry formulas (PDF)
First law and workEnthalpy changesEntropy, Gibbs energy and equilibrium

First law and work

  • ΔU=q+w  (w=−Pext​ΔV for expansion)
  • Reversible isothermal

    w=−2.303nRTlogV1​V2​​
  • ΔH=ΔU+Δng​RT,Cp​−Cv​=R

Enthalpy changes

  • Hess's law

    Δr​H=∑Δf​Hproducts​−∑Δf​Hreactants​
  • From bond enthalpies

    Δr​H=∑BEbonds broken​−∑BEbonds formed​
  • Neutralisation

    ΔH≈−57.1 kJ mol−1 (strong acid + strong base)

Entropy, Gibbs energy and equilibrium

  • ΔS=Tqrev​​;ΔG=ΔH−TΔS
  • ΔG∘=−RTlnK=−2.303RTlogK;ΔG=ΔG∘+RTlnQ
  • Spontaneity

    ΔG<0 spontaneous;T=ΔSΔH​ at the switch
  • Phase change

    ΔS=TΔHtrans​​
Chemical Bonding and Molecular StructureStates of Matter