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Formula Sheets / Chemistry

Chapter 25

Haloalkanes and Haloarenes

Revise with flashcards Download this chapter (PDF) All Chemistry formulas (PDF)
SN1, SN2 and eliminationPreparation and named reactionsHaloarenes

SN1, SN2 and elimination

  • SN2

    rate=k[RX][Nu−]; inversion;  CH3​X>1∘>2∘>3∘
  • SN1

    rate=k[RX]; racemisation;  3∘>2∘>1∘; polar protic solvent
  • Leaving group

    I−>Br−>Cl−>F−
  • Saytzeff

    elimination gives the more substituted alkene

Preparation and named reactions

  • Finkelstein: RCl+NaI→RI;Swarts: RBr+AgF→RF
  • Sandmeyer: ArN2+​CuX​ArX;Wurtz–Fittig: ArX+RX+Na→ArR

Haloarenes

  • less reactive to nucleophiles (C–X has partial double-bond character);  EWG at o/p speeds up SNAr
Coordination CompoundsAlcohols Phenols and Ethers