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Formula Sheets / Physics

Chapter 15

Kinetic Theory of Gases

Revise with flashcards Download this chapter (PDF) All Physics formulas (PDF)
Ideal gas and kinetic theoryMolecular speeds and mean free pathDegrees of freedom and specific heats

Ideal gas and kinetic theory

  • PV=nRT=NkB​T,P=31​ρvrms2​
  • Average KE

    Eˉ=23​kB​T per molecule (translational)

Molecular speeds and mean free path

  • vrms​=M3RT​​,vavg​=πM8RT​​,vmp​=M2RT​​
  • Mean free path

    λ=2​πd2n1​=2​πd2PkB​T​

Degrees of freedom and specific heats

  • Equipartition

    21​kB​T per degree of freedom;U=2f​nRT
  • Cv​=2f​R,Cp​=Cv​+R,γ=1+f2​
  • Values of f

    monatomic 3 (γ=35​);diatomic 5 (γ=57​);non-linear polyatomic 6 (γ=34​)
  • Mixture

    Cv​=n1​+n2​n1​Cv1​+n2​Cv2​​
ThermodynamicsOscillations