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Formula Sheets / Chemistry

Chapter 3

Classification of Elements and Periodicity in Properties

Revise with flashcards Download this chapter (PDF) All Chemistry formulas (PDF)
Periodic trendsElectronic configuration and blocksNomenclature (Z > 100)

Periodic trends

  • Across a period (left → right)

    atomic radius↓;  ionisation enthalpy↑;  electronegativity↑;  metallic character↓
  • Down a group

    atomic radius↑;  ionisation enthalpy↓;  electronegativity↓
  • Effective nuclear charge

    Zeff​=Z−σ (screening constant)
  • Electron gain enthalpy

    most negative: Cl>F (small size of F);noble gases positive
  • Isoelectronic species

    radius falls as nuclear charge rises: O2−>F−>Na+>Mg2+

Electronic configuration and blocks

  • s-block: ns1−2;  p-block: ns2np1−6;  d-block: (n−1)d1−10ns0−2;  f-block: (n−2)f1−14
  • Anomalous configurations

    Cr: 3d54s1;Cu: 3d104s1

Nomenclature (Z > 100)

  • 0 nil, 1 un, 2 bi, 3 tri, 4 quad, 5 pent, 6 hex, 7 sept, 8 oct, 9 enn + -ium
Structure of AtomChemical Bonding and Molecular Structure